
Kazuki Kasai1,2, Hideyuki Murakami2, Seiji Kuroda2 and Hachiro Imai1
1Division of Materials Science and Engineering, Graduate School of Shibaura Institute of Technology, Tokyo 135-8548
The effect of pre-surface treatment and crystal orientation on microstructural changes in the aluminized 4th generation Ni-based single-crystal superalloy TMS-138 was investigated. The substrate superalloy was cut along the {100} and {110} planes on which three kinds of surface finishing, such as grit-blasting, mechanically polishing and electro-polishing were conducted prior to the conventional high-activity aluminizing process. A thermal cycling test at 1373 K revealed that heavy deformation of substrate surface by grit blasting gave rise to the formation of a secondary reaction zone (SRZ) in the vicinity of interdiffusion zone/substrate interfaces. While when the surfaces were finished by electro-polishing, voids were formed in the vicinity of interdiffusion zone/substrate interfaces. It is also found that accelerated formation of SRZ and voids was observed along < 110 > directions rather than < 100 > directions during the thermal cycling test. The difference in morphological changes of substrates can be related to the residual stress introduced by the surface finishing.
(Received 2009/5/1)
secondary reaction zone (SRZ), thermal barrier coatings (TBC), aluminizing, nickel-based single crystal superalloys
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