日本金属学会誌

J. Japan Inst. Metals, Vol. 63, No. 6 (1999),
pp. 741-746

Theoretical Investigation for the Formation Mechanism ofCuAu-I Type Ordered Structure in InGaAs/(110)InP Alloy
Semiconductor Using an Empirical Interatomic Potential

Yoshihiro Kangawa1, Noriyuki Kuwano2,Kensuke Oki2 and Tomonori Ito3

1Department of Materials Science and Technology, Graduate School of Engineering Sciences, Kyushu University, Fukuoka 816-8580
2Department of Applied Science for Electronics and Materials, Graduate School of Engineering Sciences, Kyushu University, Fukuoka 816-8580

3NTT System Electronics Laboratories, Atsugi 243-1098

Abstract:

It is known that a CuAu-I (L10) type ordered structure is formed in an (In, Ga)As alloy semiconductor grown on a slightly tilted (110)InP substrate. The energy gains due to the formation of L10 in a bulk alloy, in a thick epi-layer and in a single epi-layer on a two-monolayer step, were investigated using an empirical interatomic potential calculation. It is confirmed that an L10 ordered structure is not stable in a bulk alloy. The ordered structure can exist stably in a thick epi-layer, but the energy gain due to the ordering is too small to form the ordered structure at the growth temperature. The L10 ordered structure can actually form at a two-monolayer step on the growth-surface. This indicates that the atomic arrangement near the two-monolayer step has strong effects on the stability of the ordered structure in an (In, Ga)As alloy.


(Received January 12, 1999; In Final Form March 24, 1999)

Keywords:

InGaAs, CuAu-I type ordered structure, empirical interatomic potential, epitaxial growth, two-monolayer step, alloy semiconductor


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