日本金属学会誌

J. Japan Inst. Metals, Vol. 53, No. 3 (1989),
pp. 322-326

In-situ Observation of Chloride Ion in Iron Pit

Tadahiko Mizuno1

1Department of Nuclear Engineering, Faculty of Engineering, Hokkaido University, Sapporo

Abstract:

Pitting corrosion of pure iron in borate buffer solution was studied by in-situ technics using chloride isotope 36Cl. Relationships between chloride ion concentration and current density in pit during pitting corrosion was discussed. Some results are summarized as follows.
(1)  Pits growth process is divided into two steps by the variation of chloride ion concentration and pitting current with time.
The first step: chloride ion concentration on a pit surface (γ p) increases linearly with time while the current density (ip) stays constant.
The second step: γ p stays at a constant, on the other hand, ip decreases gradually with time.
(2)  Both of γ p and ip increase with external electrode potential.
(3)  Also γ p and ip increase with a logarithmic low of the chloride ion concentration in a bulk solution.


(Received 1988/10/17)

Keywords:

pitting corrosion, chloride ion concentration, pitting current density, chloride isotope, in-situ measurment, pure iron, borate buffer solution


PDF(Free)PDF (Free)     Table of ContentsTable of Contents

Please do not copy without permission.