日本金属学会誌

J. Japan Inst. Metals, Vol. 21, No. 10 (1957),
pp. 587-589

Degassing of Copper (1st Report)

Taro Ohtsuki


Abstract:

The results show that (1) the gas evolved from copper manufactured by deoxidizing with hydrogen consists mainly in H2 over the temperature range 860° to 960° and the diffusion coefficient of H2 in copper is represented by the relation D=2 × 10-3 exp (-15,000/RT) cm2·sec-1. (2) the gas evolved from copper manufactured by deoxidizing with magnesium consists mainly in H2, with smaller amounts of CO, CO2 and H2O at the temperature 610~975° and the relation between the quantity of gas and temperature is at random, because magnesium included in copper diffuses and evaporates on heating in vacuum and cleaning action of the gas evolved from copper by a part of the magnesium content takes place.


(Received 1957/6/10)

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