Materials Transactions, Vol.51 No.01 (2010) pp.78-84
© 2010 The Japan Institute of Light Metals

Effects of Alloying Elements in Aluminum Alloys and Activations on Zincate Treatment and Electroless Nickel-Phosphorus Plating

Koji Murakami¹, Makoto Hino¹, Ryosuke Furukawa² and Teruto Kanadani²

Zincate treatment and electroless nickel-phosphorus plating for aluminum alloys of A1100, A2017, A5052 and A7075 were researched from the viewpoints of alloying elements and activation conducted prior to zincate treatment. Surface morphologies of zincated surfaces, electrochemical properties during zincate treatment and depth profiles on activated and zincated surfaces were investigated by microscopy and measurement of temporal changes of electrode potential.
Adhesion strengths of the plated films were measured by 90° peeling test, which showed that double zincate treatment improved adhesion strength especially when ferric ion was added into the zincate solution except for the case of A7075. Temporal changes of electrode potential during zincate treatments and morphologies of the zincated surfaces showed that copper and zinc promoted uniform precipitation of zinc and resulting rapid termination of conversion reaction. Excess zinc was shown to dissolve into the plating solution and cause the formation of low-density area or gaps between plated films and substrates.
Activation for A1100 by various conditions showed that formation of oxide film had a remarkable effect on precipitation of zinc during zincate treatment. When a mixture of nitric and hydrofluoric acid was used for activation, finer particles of zinc were formed near etch pits compared with the cases of hydrochloric or nitric acid. On the other hand, the surface was uniformly covered with fine zinc particles in the case of the activation with a solution of sodium hydroxide. This indicates that uniformity of oxide film on substrate before zincate treatment is thought to bring about uniform precipitation of zinc.

(Received 2009/8/17; Accepted 2009/9/28; Published 2009/12/2)

Keywords: aluminum alloys, zincate treatment, electroless nickel-phosphorus plating, alloying elements, activation

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REFERENCES

1. A. Brenner and G. E. Riddell: Proc. Am. Eectroplaters Soc. 33 (1946) 23–29.
2. A. Brenner and G. E. Riddell: Proc. Am. Eectroplaters Soc. 34 (1947) 156–170.
3. G. Gutzeit: Plating 46 (1959) 1158–1164.
4. G. Gutzeit: Plating 47 (1960) 63–70.
5. H. Darmstadt, M. Garcia-Perez, A. Adnot, A. Chaala, D. Kretschmer and C. Roy: Energy Fuels 18 (2004) 1291–1301.
6. Q. Lu, J. Zhang and X. Zhu: Chinese Sci. Bull. 53 (2008) 3726–3734.
7. O. Seri and Y. Kido: Mater. Trans. 50 (2009) 1433–1439.
8. O. Seri and Y. Kido: J. Japan Inst. Light Metals 59 (2009) 359–364 (in Japanese).
9. M. Pourbaix: Atlas of Electrochemical Equilibria in Aqueous Solutions, National Association of Corrosion Engineers, Houston, TX (1974) 168–176.
10. M. Yabe: J. Surf. Fin. Soc. Jpn. 48 (1997) 522–529 (in Japanese).
11. F. Keller and W. G. Zelley: J. Electroc. Soc. 97 (1950) 143–151.
12. M. Hino, K. Murakami, M. Hiramatsu, K. Chen, A. Saijo and T. Kanadani: Mater. Trans. 46 (2005) 2169–2175.
13. K. Murakami, M. Hino, M. Hiramatsu, K. Osamura and T. Kanadani: Mater. Trans. 47 (2006) 2518–2523.
14. K. Tashiro, K. Chiba, Y. Fukuda, H. Nakao and H. Honma: J. Surf. Fin. Soc. Jpn. 45 (1994) 720–725 (in Japanese).
15. K. Azumi, Y. Fujishige, M. Seo, L. Nanis, H. Nakao and K. Tashiro: J. Surf. Fin. Soc. Jpn. 47 (1996) 529–535 (in Japanese).
16. K. Murakami, M. Hino, M. Hiramatsu, K. Osamura and T. Kanadani: Mater. Sci. Forum 519–521 (2006) 759–764.
17. K. Azumi, Y. Fujishige, M. Seo, L. Nanis, H. Nakao and K. Tashiro: J. Surf. Fin. Soc. Jpn. 47 (1996) 802–807 (in Japanese).
18. K. Azumi, Y. Koyama and S. Kawashima: J. Surf. Fin. Soc. Jpn. 54 (2003) 422–427 (in Japanese).
19. T. Morikawa, T. Nakade and M. Yokoi: J. Surf. Fin. Soc. Jpn. 59 (2008) 257–264 (in Japanese).
20. K. Murakami, M. Hiramatsu, M. Hino, K. Sueoka and R. Nakanishi: J. Surf. Fin. Soc. Jpn. 58 (2007) 280–286 (in Japanese).
21. Edited by A. Kamio et al.: Aruminiumu-no-soshiki-to-seishitsu, Japan Inst. Light Metals (1991) p. 271 (in Japanese).
22. O. Seri: Kinzokuzairyou-no-fushoku-to-bousyoku-no-kiso, Seizando (2006) p. 143 (in Japanese).
23. S. Egoshi, K. Azumi, M. Seo, S. Kawashima and Y. Koyama: Proc. 113th Annual Conf. Surf. Fin. Soc. Japan (2006) p.181 (in Japanese).
24. K. Azumi, K. Nishimura, T. Kurihara and M. Seo: J. Surf. Fin. Soc. Jpn. 55 (2004) 555–559 (in Japanse).

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