Materials Transactions Online

Materials Transactions, Vol.46 No.02 (2005) pp.379-381
© 2005 The Japan Institute of Metals

Structural Analysis of Melt-Spun MgxPd100-x (x=70, 80, 85 and 90) Amorphous Alloys

Sumiaki Nakano1,, Sin-ichi Yamaura2, Akiko Kitano3, Masugu Sato3, Norimasa Umesaki3, Sakae Uchinashi1, Hisamichi Kimura2 and Akihisa Inoue2

1Research & Development Center, Home Appliances Manufacturing Division Company, Matsushita Electric Works, Ltd., Kadoma 571-8686, Japan
2Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
3Materials Science Division, Japan Synchrotron Radiation Research Institute, Mikazuki 679-5198, Japan

MgxPd100-x (x=70, 80, 85 and 90) amorphous alloys were prepared by the single-roller melt-spinning technique and X-ray diffractometry was performed with synchrotron radiation using the large Debye-Scherrer camera installed at SPring-8. As a result, it has been shown that a medium-range order (MRO) exists in each of the amorphous alloys and that the MRO decreases monotonously with increasing the Mg content. Additionally, it has also been shown that the atomic distances of first neighbor pairs hardly vary although the rate of the coordination numbers varies monotonously with the alloy composition.

(Received 2004/12/7; Accepted 2005/1/12)

Keywords: amorphous, magnesium-palladium alloy, X-ray diffraction, large Debye-Scherrer camera

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REFERENCES

  1. S. Nakano, S. Yamaura, S. Uchinashi, H. M. Kimura and A. Inoue: Collected Abstracts of the 84th National Meeting of the Chemical Society of Japan (2004) p.~417.
  2. S. Nakano, S. Yamaura, S. Uchinashi, H. M. Kimura and A. Inoue: Mater. Trans. 45 (2004) 1367--1370.
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  6. M. Sato, T. Matsunaga, T. Kouzaki, N. Yamada, Mat. Res. Soc. Symp. Proc. 803 (2004) 245--250.


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